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Pearson Edexcel International GCSE (9–1) · CHEMISTRY · Section

Structural isomerism in the alkanes

19 practice questions

Practice questions

11–19 of 19

  1. Question 11

    3 marks · Normal

    A hydrocarbon has the molecular formula C6H14. How many structural isomers are possible for C6H14? Show your reasoning.

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  2. Question 12

    3 marks · Normal

    Explain how you would decide whether two structures for C5H12 drawn below are isomers or not.

    Structure 1: CH3–CH2–CH2–CH2–CH3 Structure 2: CH3–CH(CH3)–CH2–CH3

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  3. Question 13

    4 marks · Normal

    The following table gives the molecular formulae and numbers of structural isomers possible for members of the alkane series:

    AlkaneMolecular formulaNumber of isomers
    MethaneCH41
    EthaneC2H61
    PropaneC3H81
    ButaneC4H102
    PentaneC5H123
    HexaneC6H14?
    (a)

    Compare the number of isomers as the number of carbon atoms increases from C4H10 to C6H14.

    [1 mark]
    (b)

    Explain why the number of structural isomers increases as you go from C4H10 to C6H14.

    [2 marks]
    (c)

    Use the data to predict the number of isomers for C6H14.

    [1 mark]
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  4. Question 14

    1 mark · Normal

    Which statement is true about structural isomers?

    1. A.They have the same molecular and structural formulae.
    2. B.They have the same atoms joined in a different order.
    3. C.They are different elements with the same mass number.
    4. D.They all have a straight chain structure.
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  5. Question 15

    2 marks · Normal

    State one difference and one similarity between structural isomers.

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  6. Question 16

    4 marks · Normal

    Heptane (C7H16) is an alkane. Answer the following about its isomers.

    (a)

    Explain why heptane can form structural isomers.

    [1 mark]
    (b)

    Draw the skeletal formula of two different isomers of C7H16.

    [2 marks]
    (c)

    State one feature that all isomers of C7H16 share.

    [1 mark]
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  7. Question 17

    2 marks · Hard

    Explain why two different molecules with the formula C6H14 are considered structural isomers.

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  8. Question 18

    5 marks · Hard

    This question is about structural isomerism in the alkanes.

    (a)

    Complete the following table for alkanes, giving the number of possible structural isomers for each formula.

    Molecular formulaNumber of structural isomers
    C3H8
    C4H10
    C5H12
    [3 marks]
    (b)

    Explain why C5H12 has more structural isomers than C3H8.

    [2 marks]
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  9. Question 19

    2 marks · Hard

    Explain why it is not possible to have a structural isomer of methane (CH4).

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