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Pearson Edexcel International GCSE (9–1) · CHEMISTRY · Unit

Principles of Chemistry

991 practice questions

Topics covered

Practice questions

121–130 of 161 · Hard

  1. Question 121

    8 marks · Hard

    This question is about the differences in properties between substances with simple molecular structures and those with giant covalent structures.

    (a)

    Explain why substances with simple molecular structures, such as chlorine (Cl₂), have low melting and boiling points.

    [2 marks]
    (b)

    Diamond and graphite are both forms of carbon, but diamond is much harder than graphite. Explain, in terms of structure and bonding, why diamond is harder than graphite.

    [3 marks]
    (c)

    State and explain whether Cl₂ can conduct electricity. Then compare this with the ability of diamond to conduct electricity, explaining your reasoning.

    [3 marks]
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  2. Question 122

    7 marks · Hard

    This question is about how the physical properties of substances are linked to their structures and electrical conductivity.

    (a)

    The table shows data for some simple molecular and giant covalent substances:

    Melting and boiling points of selected substances.
    SubstanceRelative molecular mass / MrMelting point / °CBoiling point / °C
    Chlorine (Cl₂)71-101-34
    Bromine (Br₂)160-759
    Iodine (I₂)254114184
    Diamond–35504830
    [0 marks]
    (b)

    Using data from the table, describe and explain how the melting and boiling points of the halogens change as the relative molecular mass increases.

    [2 marks]
    (c)

    Explain why the melting point of diamond is much higher than those of the halogens listed, using ideas about structure and bonding.

    [2 marks]
    (d)

    State whether graphite conducts electricity. Suggest, based on your knowledge of its structure, why this is different from diamond and the halogens.

    [3 marks]
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  3. Question 123

    7 marks · Hard

    This question is about how the type of structure affects properties in covalent and giant covalent substances.

    (a)

    Explain what is meant by a 'simple molecular structure', using water (H₂O) as an example.

    [2 marks]
    (b)

    Compare the structure and bonding found in C₆₀ fullerene with that in graphite.

    [3 marks]
    (c)

    State which would have a higher melting point, graphite or C₆₀ fullerene. Explain your answer in terms of their bonding and structures.

    [2 marks]
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  4. Question 124

    2 marks · Hard

    Explain, in terms of electrostatic forces, how metallic bonding holds a pure metal such as aluminium together. Your answer should refer specifically to the particles involved.

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  5. Question 125

    5 marks · Hard

    Zinc is used to galvanise iron to prevent rusting because it is strong and resistant. Answer the following about the properties of zinc metal and its bonding.

    (a)

    State and explain, in terms of metallic bonding, why zinc conducts electricity.

    [2 marks]
    (b)

    Zinc can be hammered into thin sheets. Explain why this is possible, referring to its structure and bonding.

    [2 marks]
    (c)

    Zinc has a high melting point. Explain this property in terms of attraction between its particles.

    [1 mark]
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  6. Question 126

    2 marks · Hard

    Draw a simple 2D diagram to represent the arrangement of particles in a piece of barium metal. Clearly label the positive ions and the sea of delocalised electrons.

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  7. Question 127

    2 marks · Hard

    Explain why pure, solid silver chloride does not conduct electricity, but when dissolved in water, it does.

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  8. Question 128

    5 marks · Hard

    A teacher tests the electrical conductivity of four substances in different states. The results are shown in the table below.

    Conductivity of substances in different states
    SubstanceStateConducts electricity?
    Potassium nitrateSolidNo
    Potassium nitrateAqueousYes
    Sulfur dioxideLiquidNo
    Lead(II) bromideMoltenYes
    (a)

    Identify which of the substances in the table are ionic compounds.

    [1 mark]
    (b)

    Explain why potassium nitrate conducts electricity when dissolved in water but not as a solid.

    [2 marks]
    (c)

    Suggest why sulfur dioxide does not conduct electricity, even when liquid. Use your knowledge of bonding.

    [2 marks]
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  9. Question 129

    2 marks · Hard

    Explain, with reference to structure and particles, why molten lead(II) bromide can conduct electricity.

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  10. Question 130

    2 marks · Hard

    State the name given to (a) the positive electrode and (b) the liquid or solution that contains ions and undergoes electrolysis. Give both answers.

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