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Pearson Edexcel International GCSE (9–1) · CHEMISTRY · Unit

Principles of Chemistry

991 practice questions

Topics covered

Practice questions

411–420 of 423 · Normal

  1. Question 411

    3 marks · Normal

    A student wants to find out whether substance X is an ionic compound, a covalent compound (non-electrolyte), or an acid using an experiment. She sets up the following experiment in which two carbon electrodes are placed in a solution of substance X, connected to a power supply and a bulb, as shown in the diagram:

    Apparatus: beaker (solution of X), test tube (carbon electrode), test tube (carbon electrode)carbon electrodecarbon electrodesolution of X
    Apparatus for testing conductivity.

    In three separate experiments she uses:

    TestSubstance in solutionObservation
    AX dissolved in waterBulb does not light up
    BMolten XBulb lights up
    CAqueous acidBulb lights up

    Using the data above, calculate whether substance X is ionic, covalent (non-electrolyte), or an acid. Explain your reasoning.

    Answer and see the solution →
  2. Question 412

    6 marks · Normal

    Potassium iodide (KI) is an ionic compound. When heated until molten and electrolysed using inert electrodes, iodine gas is produced at one electrode and potassium metal at the other.

    (a)

    State the ions present in molten potassium iodide.

    [1 mark]
    (b)

    Write the half-equation for the reaction occurring at the cathode.

    [1 mark]
    (c)

    Write the half-equation for the reaction occurring at the anode.

    [1 mark]
    (d)

    State, in terms of electron transfer, which reaction involves reduction and which involves oxidation.

    [2 marks]
    (e)

    Explain how you can use the mnemonic OILRIG to identify which reaction at the electrodes is oxidation and which is reduction.

    [1 mark]
    Answer and see the solution →
  3. Question 413

    6 marks · Normal

    A student carries out the electrolysis of molten calcium chloride (CaCl2) in a laboratory using inert carbon electrodes.

    (a)

    State what is meant by 'discharging an ion' during electrolysis.

    [2 marks]
    (b)

    Identify the ions in molten calcium chloride and their movement during electrolysis.

    [1 mark]
    (c)

    Write the half-equation for the discharge of chloride ions at the anode.

    [1 mark]
    (d)

    Explain, using electron transfer, what happens to a calcium ion during electrolysis.

    [2 marks]
    Answer and see the solution →
  4. Question 414

    6 marks · Normal

    A student sets up an electrolysis experiment using molten potassium iodide (KI). An external circuit with a bulb lights up when the current is switched on.

    (a)

    State the ions present in molten potassium iodide. Identify which ions move towards the cathode and which move towards the anode during electrolysis.

    [2 marks]
    (b)

    Write the ionic half-equation for the reaction occurring at the cathode.

    [1 mark]
    (c)

    Write the ionic half-equation for the reaction occurring at the anode.

    [1 mark]
    (d)

    For the electrode reaction at the cathode, state whether it is an oxidation or a reduction. Justify your answer using the concept of electron transfer.

    [2 marks]
    Answer and see the solution →
  5. Question 415

    6 marks · Normal

    During the electrolysis of molten calcium chloride (CaCl2), calcium forms at one electrode and chlorine gas is released at the other.

    (a)

    Write the balanced ionic half-equation for the reaction at the electrode where chlorine gas is produced.

    [2 marks]
    (b)

    Explain what is meant by the term 'discharging an ion' using Ca^2+ or Cl^- as an example from this electrolysis process.

    [2 marks]
    (c)

    Recall the meaning of the mnemonic OILRIG and use it to decide whether the reaction at the chlorine-producing electrode is an oxidation or a reduction.

    [2 marks]
    Answer and see the solution →
  6. Question 416

    8 marks · Normal

    A student is given a mixture of table salt (sodium chloride) and sand. She wants to separate the components and measure the solubility of sodium chloride at 20°C.

    (a)

    Describe a method the student could use to separate the sand from the salt in the mixture. Include the main steps and the name of each process.

    [2 marks]
    (b)

    After separation, the student makes a saturated solution of sodium chloride in 50 g of water at 20°C. She filters the solution to remove any excess solid, then evaporates the water and obtains 18.6 g of dry sodium chloride crystals.

    Use these results to calculate the solubility of sodium chloride in water (in g per 100 g water) at 20°C.

    [3 marks]
    (c)

    In a different experiment, the student runs a paper chromatography investigation using three coloured inks from different pens. The chromatogram develops as shown below (all spots and the solvent front are marked by distance from the pencil line):

    Chromatogram data
    PenColourDistance moved by spot (cm)Distance moved by solvent front (cm)
    Ablue2.47.0
    Bred6.17.0
    Cgreen4.27.0

    Calculate the R_f value for the green dye (Pen C).

    [1 mark]
    (d)

    Explain how a comparison of R_f values can help identify whether two pens use the same dye.

    [2 marks]
    Answer and see the solution →
  7. Question 417

    8 marks · Normal

    For each gap in the sentences or statements below, write the correct word or phrase. You may use each answer once or not at all.

    Word list: solute compound element solution mixture saturated solubility solvent

    (a)

    (i) A substance made of only one type of atom is called an _____.

    [1 mark]
    (b)

    (ii) A substance formed when two or more elements chemically combine is a _____.

    [1 mark]
    (c)

    (iii) A _____ contains different substances mixed together, not chemically joined.

    [1 mark]
    (d)

    (iv) The part of a solution that dissolves another substance is the _____.

    [1 mark]
    (e)

    (v) The dissolved solid in a solution is called the _____.

    [1 mark]
    (f)

    (vi) A _____ solution contains as much dissolved solute as possible at a particular temperature.

    [1 mark]
    (g)

    (vii) The _____ of a substance is the maximum mass that dissolves in 100 g of solvent at a specific temperature.

    [2 marks]
    Answer and see the solution →
  8. Question 418

    8 marks · Normal

    A student wants to investigate the solubility of a compound and check whether a white powder she found is a pure substance or a mixture.

    (a)

    Outline an experiment to measure the solubility of a solid in water at 40°C. State the key steps and the measurements you would record.

    [3 marks]
    (b)

    The student measures the melting point of the powder. She finds that it melts over a range from 76°C to 83°C. Explain what this result suggests about the nature of the powder.

    [2 marks]
    (c)

    Describe how melting point measurements can be used to distinguish between a pure substance and a mixture. Give an example with data.

    [3 marks]
    Answer and see the solution →
  9. Question 419

    8 marks · Normal

    A mixture of potassium nitrate and sand is supplied to a student. She performs a series of experiments to separate the components and calculate solubility.

    (a)

    Describe the two separation techniques needed to obtain pure, dry potassium nitrate from the mixture.

    [2 marks]
    (b)

    The student adds the mixture to 40.0 g of water and stirs until no more potassium nitrate dissolves. After filtration, she evaporates the solution to recover 22.8 g of dry potassium nitrate. Calculate the solubility of potassium nitrate in water at this temperature (in g per 100 g water).

    [3 marks]
    (c)

    If the solubility of potassium nitrate at 60°C is 110 g per 100 g of water, and at 30°C it is 45 g per 100 g water, calculate the mass of potassium nitrate that will crystallise out when a saturated solution containing 110 g of potassium nitrate in 100 g water at 60°C is cooled to 30°C.

    [2 marks]
    (d)

    State why it is important to use filtration after dissolving the mixture in water.

    [1 mark]
    Answer and see the solution →
  10. Question 420

    8 marks · Normal

    This question is about writing balanced equations (with state symbols) and using them to perform gas volume calculations.

    (a)

    Magnesium reacts with steam to produce magnesium oxide and hydrogen gas. Write a balanced chemical equation for this reaction, including state symbols.

    [2 marks]
    (b)

    Calculate the maximum volume, in cm³, of hydrogen gas formed at rtp when 3.60 g of magnesium is reacted with excess steam. (Ar: Mg = 24.0; molar volume at rtp = 24,000 cm³ mol⁻¹)

    [4 marks]
    (c)

    State one reason why the actual volume of hydrogen collected in an experiment might be less than your calculated answer.

    [2 marks]
    Answer and see the solution →