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Question 54 of 144 in Chemical Formulae, Equations and Calculations Part 2

Using the molar volume in calculations with chemical equations

4 marks · Normal

Ammonium nitrate decomposes to form dinitrogen oxide (N2O) and water. The balanced equation is:

A practical uses 8.0 g of ammonium nitrate. (Ar: N = 14, H = 1, O = 16; molar volume at rtp = 24 dm³)

(a)

Calculate the number of moles of ammonium nitrate used.

[2 marks]
(b)

Calculate the volume, in dm³, of dinitrogen oxide (N₂O) formed at rtp.

[2 marks]

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(a) 0.10 mol

(b) 2.4 dm³ dm^3

Show mark scheme and worked solution

Marking points

M1 (a) · 1 mark · Finds Mr of NH₄NO₃ (14×2 + 4×1 + 3×16 = 80)

A1 (a) · 1 mark · Correct calculation of moles (8.0/80 = 0.10 mol) (follow-through)

M2 (b) · 1 mark · Uses equation 1:1 mole ratio for N₂O

A2 (b) · 1 mark · Multiplies by proper molar volume (0.10 × 24 = 2.4 dm³, accept ecf) (follow-through)

Worked solution

a) Calculate Mr of NH₄NO₃: (2×14) + (4×1) + (3×16) = 28 + 4 + 48 = 80

b) 1 mole NH₄NO₃ produces 1 mole N₂O. So moles of N₂O = 0.10

Volume = moles × molar volume = 0.10 × 24 = 2.4 dm³

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