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Question 88 of 198 in Electrolysis

The electrolysis of other molten substances

4 marks · Normal
Student equations for the electrolysis of molten calcium bromide
StudentCathode equationAnode equation
ACa^{2+} + 2e^- \to Ca2Br^- \to Br_2 + 2e^-
BCa^{2+} \to Ca + 2e^-Br^- \to Br_2 + 2e^-
CCa^{2+} + e^- \to Ca2Br^- \to Br_2 + 2e^-
DCa^{2+} + 2e^- \to Ca2Br^- \to Br_2 + e^-

Use the table above. For each equation below, state which students wrote it correctly. For each incorrect equation, explain the mistake.

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Common mistakes: Omitting electrons; Incorrect numbers of electrons

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Marking points

B1 · 1 mark · Identifies student(s) with correct cathode half-equation (Student A and D only)

B2 · 1 mark · Identifies student(s) with correct anode half-equation (Student A only)

E1 · 1 mark · Explains at least one cathode equation error (e.g., B: electrons on wrong side, not balanced for charge; C: wrong number of electrons)

E2 · 1 mark · Explains at least one anode equation error (e.g., B: not balanced for atoms; D: wrong number of electrons)

Worked solution

Correct cathode equation: Students A and D.

Correct anode equation: Only Student A.

B (cathode): No electrons on the left side, so charges do not balance.

C (cathode): Only one electron, but Ca^{2+} needs to gain 2 electrons to become Ca.

B (anode): Only one Br^- ion used, but Br2 molecule needs two Br atoms; atoms are not balanced.

D (anode): Only one electron given off, but 2Br^- ions collectively lose 2 electrons when forming Br2.

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