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Question 184 of 198 in Electrolysis

What would happen with non-electrolytes?

3 marks · Normal

A student wants to find out whether substance X is an ionic compound, a covalent compound (non-electrolyte), or an acid using an experiment. She sets up the following experiment in which two carbon electrodes are placed in a solution of substance X, connected to a power supply and a bulb, as shown in the diagram:

Apparatus: beaker (solution of X), test tube (carbon electrode), test tube (carbon electrode)carbon electrodecarbon electrodesolution of X
Apparatus for testing conductivity.

In three separate experiments she uses:

TestSubstance in solutionObservation
AX dissolved in waterBulb does not light up
BMolten XBulb lights up
CAqueous acidBulb lights up

Using the data above, calculate whether substance X is ionic, covalent (non-electrolyte), or an acid. Explain your reasoning.

Work this out on paper, then compare with the answer and worked solution below. With a free account you can submit written answers for marking.

Show answer

Ionic. Substance X is ionic because it only conducts electricity when molten, not when dissolved in water.

Also accept: X is ionic because it does not conduct in solution but does when molten.; It is an ionic compound, as only molten ionic substances conduct electricity, not covalent or non-electrolyte.

Common mistakes: Suggesting X is covalent because it does not conduct in solution.; Suggesting X is an acid because an aqueous acid conducts electricity.

Show mark scheme and worked solution

Marking points

M1 · 1 mark · Identifies from the data that molten X conducts electricity but solution of X does not.

M2 · 1 mark · States that this is behaviour expected of ionic compounds: ionic solids conduct when molten, not when in solution if insoluble.

A1 · 1 mark · Conclusion: substance X is ionic.

Worked solution

In test A, when X is dissolved in water, the bulb does not light up, so X in solution does not conduct electricity.

In test B, molten X conducts electricity (bulb lights up). In test C, an aqueous acid conducts electricity.

Since X conducts only when molten and not in solution, it must be an ionic compound that is insoluble or only molten ionic compounds conduct. Covalent (non-electrolytes) do not conduct in any state, and acids conduct when in solution.

Therefore, X is ionic.

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