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Question 709 of 991 in Principles of Chemistry

Simple molecular structures

3 marks · Easy

The table shows properties of two substances, X and Y.

Properties of X and Y
SubstanceRelative molecular mass (Mr)Physical state at room temp.Electrical conductivity
X32gasdoes not conduct
Y160liquiddoes not conduct
(a)

Which substance, X or Y, has the higher boiling point? Explain your answer.

[2 marks]
(b)

Suggest why neither substance conducts electricity.

[1 mark]

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(a) Y has the higher boiling point because it has a higher Mr, leading to stronger intermolecular forces that require more energy to overcome. · must show Correct identification of Y; explanation referencing Mr and intermolecular forces

(b) No mobile charged particles (ions or electrons) in simple molecular substances. · must show recognition of lack of mobile charge carriers

Show mark scheme and worked solution

Marking points

B1 (a) · 1 mark · Correctly identifies Y as the substance with the higher boiling point.

M1 (a) · 1 mark · Explains this is due to higher Mr (relative molecular mass) resulting in stronger intermolecular forces.

B1 (b) · 1 mark · Mentions lack of mobile charged particles; simple molecules do not have ions/electrons free to move.

Worked solution

a) Y has the higher boiling point. This is because Y has a higher relative molecular mass (160 compared to 32), so it has stronger intermolecular forces between its molecules. More energy is required to separate these molecules, resulting in a higher boiling point.

b) Neither X nor Y conducts electricity because simple molecular substances have no charged particles (like ions or free electrons) that can move to carry current.

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