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Question 61 of 68 in Covalent Bonding

Covalent Bonding

5 marks · Easy
(a)

Draw a dot-and-cross diagram to show the covalent bonding in a molecule of ammonia (NH).

[2 marks]
(b)

Explain why ammonia is a gas at room temperature, using your understanding of intermolecular forces.

[2 marks]
(c)

State how many lone pairs of electrons are present on the nitrogen atom in the ammonia molecule.

[1 mark]

Work this out on paper, then compare with the answer and worked solution below. With a free account you can submit written answers for marking.

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(a) Diagram showing N atom in centre, three shared pairs (one dot and one cross) to each of three H atoms, and one lone pair of electrons on N. · must show One lone pair on nitrogen, Three single bonds to three hydrogens

(b) Ammonia has a simple molecular structure with weak intermolecular forces, so not much energy is required to overcome them. Therefore, ammonia is a gas at room temperature.

(c) 1

Must show: Central N atom with three covalent bonds to H atoms; correct lone pair

Also accept: Any correct diagram with three single bonds, correct lone pair

Common mistakes: Missing lone pair on N; Incorrect number of bonds

Show mark scheme and worked solution

Marking points

D1 (a) · 1 mark · Correct dot-and-cross diagram: N in centre, 3 single bonds to H atoms (with each bond as a shared dot and cross).

A1 (a) · 1 mark · One lone pair on N atom represented correctly.

M1 (b) · 1 mark · Mentions weak intermolecular forces in ammonia.

A2 (b) · 1 mark · Links weak intermolecular forces to low energy required for boiling; explains gaseous state at room temp.

B1 (c) · 1 mark · States '1' as the number of lone pairs on nitrogen atom.

Worked solution

a) Ammonia (NH3) dot-and-cross diagram:

Geometry diagram with points N, H, H, H• x••NHHH
Dot-and-cross diagram for NH3

b) Ammonia is a gas at room temperature because its molecules are held together by weak intermolecular forces, so only a small amount of energy is needed for the molecules to escape to the gas phase.

c) Nitrogen in ammonia has 1 lone pair of electrons.

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