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Question 658 of 991 in Principles of Chemistry

The physical properties of ionic substances

2 marks · Hard

Describe the arrangement of sodium and chloride ions in the giant ionic lattice of sodium chloride.

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Each sodium ion is surrounded by six chloride ions and each chloride ion is surrounded by six sodium ions. This pattern repeats throughout the crystal.

Also accept: Each Na^+ is surrounded by 6 Cl^- ions, each Cl^- by 6 Na^+ ions, in a regular repeating pattern.

Common mistakes: Saying sodium chloride forms molecules.; Not mentioning the number of neighbouring ions.

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Marking points

B1 · 1 mark · States Na^+ surrounded by six Cl^- and Cl^- by six Na^+ ions.

B2 · 1 mark · References repeating/regular pattern throughout the structure (giant lattice).

Worked solution

In sodium chloride, each sodium ion (Na^+) is surrounded by six chloride ions (Cl^-), and each chloride ion is surrounded by six sodium ions. This arrangement repeats throughout the giant lattice.

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