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Question 94 of 198 in Electrolysis

The electrolysis of other molten substances

2 marks · Hard

Write the ionic half-equation for the reaction that occurs at the cathode during the electrolysis of molten magnesium oxide (MgO).

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Mg^{2+} + 2e^{-} \rightarrow Mg

Must show: Mg^{2+} ion on left, 2 electrons on left, Mg atom on right, Correct charge and atom balance

Common mistakes: Placing electrons on the right; Using the wrong number of electrons; Writing an unbalanced equation

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Marking points

M1 · 1 mark · Shows electrons are gained by Mg^{2+} to form Mg

A1 · 1 mark · Equation is fully balanced; two electrons and charges/atoms balanced

Worked solution

At the cathode, Mg^{2+} ions gain electrons (are reduced) to form Mg:

Balance: 1 Mg atom on both sides; left charge (+2) + (–2) = 0 matches right (neutral).

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