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Question 53 of 86 in The Halogens

Displacement reactions as redox reactions

4 marks · Normal

Two students discuss the reaction between chlorine and potassium iodide solution.

(a)

Write the ionic equation for this reaction, including state symbols.

[2 marks]
(b)

Explain, using the meanings of oxidation and reduction, which substance is oxidised and which is reduced in this reaction.

[2 marks]

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(a) · must show Ionic species, correct state symbols, balanced equation

(b) Iodide ions are oxidised (lose electrons) to form iodine; chlorine is reduced (gains electrons) to form chloride ions. Oxidation is loss of electrons; reduction is gain of electrons. · must show Correct identification of oxidised and reduced substances, electron transfer, definitions

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Marking points

M1 (a) · 1 mark · Correct reactants and products written as ions and molecules.

A1 (a) · 1 mark · All state symbols correct and present.

M2 (b) · 1 mark · States iodide ions are oxidised (lose electrons) and chlorine is reduced (gains electrons).

A2 (b) · 1 mark · Defines oxidation as loss and reduction as gain of electrons, or equivalent explanation.

Worked solution

a) The ionic equation is:

b) The iodide ions, I−, are oxidised because they lose electrons to become I2. Chlorine, Cl2, is reduced because it gains electrons to become Cl−. Oxidation is loss of electrons, and reduction is gain of electrons.

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