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Question 184 of 869 in Inorganic Chemistry

Showing that air contains about one-fifth oxygen

4 marks · Normal

The table shows results from an experiment to determine the composition of air.

Estimated composition of air.
GasEstimated percentage (%)
Oxygen20
Nitrogen75
Argon1
Carbon dioxide0.04
(a)

Compare the estimated percentage of nitrogen and oxygen to their approximate true values in dry air.

[2 marks]
(b)

Give two possible reasons why the estimated results might differ from the true values.

[2 marks]

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(a) Nitrogen is estimated lower than true value (75% vs 78%); oxygen is estimated lower than true value (20% vs 21%).

(b) Experimental error (such as incomplete reaction), or inaccurate volume readings; or not enough reagent / experiment not left long enough.

Common mistakes: Incomplete comparison; Only giving one reason

Show mark scheme and worked solution

Marking points

A1 (a) · 1 mark · Identifies nitrogen is estimated lower than true value (75% vs 78%).

A2 (a) · 1 mark · Identifies oxygen is estimated lower than true value (20% vs 21%).

B1 (b) · 1 mark · States one valid reason for difference (e.g., experiment not complete, reagent not in excess, gas syringe error).

B2 (b) · 1 mark · States a second valid reason (accept experimental limitations, leaks, incorrect readings).

Worked solution

a) Nitrogen and oxygen estimated are both a little lower than the approximate true values (nitrogen: 75% vs 78%; oxygen: 20% vs 21%).

b) Possible reasons: Not all oxygen reacted because the experiment was not left long enough; volume readings might have been inaccurate; reagents (copper or iron) might not have been in excess; or some gas may have leaked during the experiment.

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