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Question 867 of 869 in Inorganic Chemistry

Inorganic Chemistry

8 marks · Normal

Answer all parts about compounds and predicted properties in Group 1 and Group 7.

(a)

State the typical colour and solubility in water of sodium oxide.

[2 marks]
(b)

Potassium manganate(VII) is a purple compound. State which ion gives rise to the colour, and what colour you would observe if pure potassium chloride is dissolved in water.

[2 marks]
(c)

Predict the colour and physical state at room temperature of astatine, the halogen below iodine.

[2 marks]
(d)

Predict whether sodium astatide would be soluble in water, and what colour its solution would be. Explain your reasoning.

[2 marks]

Work this out on paper, then compare with the answer and worked solution below. With a free account you can submit written answers for marking.

Show answer

(a) Sodium oxide is a white solid; it is soluble in water. · must show white (not colourless), soluble in water

(b) The manganate(VII) ion is responsible for the purple colour. Potassium chloride when dissolved in water gives a colourless solution. · must show manganate(VII) ion gives colour, potassium chloride gives colourless solution

(c) Astatine would be a very dark grey or black solid at room temperature. · must show very dark grey or black, solid at room temperature

(d) Sodium astatide would be soluble in water and the solution would be colourless. This is because Group 1 metal salts are generally soluble and their solutions are colourless when the anion is colourless. · must show soluble in water, solution colourless, reason: Group 1 salts generally soluble, solution colourless if no coloured ions

Show mark scheme and worked solution

Marking points

B1 (a) · 1 mark · States sodium oxide is white.

B2 (a) · 1 mark · States sodium oxide is soluble in water.

B3 (b) · 1 mark · Identifies manganate(VII) ion as responsible for purple colour.

B4 (b) · 1 mark · Correctly states that potassium chloride solution is colourless.

B5 (c) · 1 mark · Predicts very dark grey or black for astatine.

B6 (c) · 1 mark · Predicts solid state at room temperature for astatine.

B7 (d) · 1 mark · Correctly predicts sodium astatide is soluble and would give a colourless solution.

B8 (d) · 1 mark · Explains solubility and lack of colour with correct reference to Group 1 compound properties.

Worked solution

a) Sodium oxide is a white solid and is soluble in water.

b) The colour comes from the manganate(VII) ion; potassium chloride gives a colourless solution when dissolved in water.

c) Astatine would be a very dark grey or black solid at room temperature.

d) Sodium astatide would be soluble in water and the solution would be colourless, because Group 1 metal salts are typically soluble and colourless unless the anion is coloured, which astatide is not.

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