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Question 207 of 869 in Inorganic Chemistry

The combustion of elements in oxygen

5 marks · Hard

Sodium and magnesium both burn in oxygen, forming new compounds. The reactions are more vigorous in pure oxygen than in air.

(a)

Write a balanced chemical equation for the reaction of sodium with oxygen.

[1 mark]
(b)

Describe what you would observe when magnesium burns in pure oxygen.

[2 marks]
(c)

Explain, using ideas about the percentage of oxygen in air, why sodium and magnesium burn more vigorously in pure oxygen than in air.

[2 marks]

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(a) \ce{4Na + O2 -> 2Na2O} · must show correct balancing, state symbols optional but accepted

(b) A bright white light is produced and a white solid forms. · must show reference to bright white light, mention of white (solid) product

(c) In pure oxygen, the higher concentration (100%) of oxygen means more oxygen is available to react with the metals. In air, only about 21% of the gas is oxygen. The increased oxygen concentration makes the reaction with sodium and magnesium more vigorous. · must show reference to oxygen concentration difference, correct link to combustion rate

Show mark scheme and worked solution

Marking points

A1 (a) · 1 mark · Correct balanced chemical equation for sodium and oxygen: \ce{4Na + O2 -> 2Na2O}

B1 (b) · 1 mark · States bright white light or flame when magnesium burns

B2 (b) · 1 mark · Mentions formation of white solid (magnesium oxide)

C1 (c) · 1 mark · States that oxygen is a higher percentage in pure oxygen than in air (100% vs 21%)

C2 (c) · 1 mark · Links higher oxygen concentration to more vigorous/faster/brighter burning

Worked solution

a) The balanced chemical equation is:

b) Magnesium burns with a bright white flame and forms a white powder (magnesium oxide).

c) In air, only about 21% is oxygen, whereas pure oxygen is 100% oxygen. The greater oxygen concentration causes sodium and magnesium to burn faster/more brightly in pure oxygen.

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