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Question 104 of 785 in Organic Chemistry

Coding for branched chains

4 marks · Normal

The compound below has five carbon atoms in its longest chain. It is shown with numbered carbon atoms, and a side chain:

(a)

Write the name of the longest chain.

[1 mark]
(b)
Geometry diagram with points 1, 2, 3, 4, 5, SideM112345
Structural formula of the molecule

Identify the type and position of the side chain shown.

[2 marks]
(c)

Give the full IUPAC name of the compound.

[1 mark]

Work this out on paper, then compare with the answer and worked solution below. With a free account you can submit written answers for marking.

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(a) pentane

(b) methyl group at position 3

(c) 3-methylpentane

Common mistakes: wrongly numbering from the incorrect end; missing the side chain type; incorrect IUPAC order

Show mark scheme and worked solution

Marking points

B1 (a) · 1 mark · Correctly gives the name of the five-carbon chain as 'pentane'.

M1 (b) · 1 mark · Correctly identifies the side chain as a methyl group.

A1 (b) · 1 mark · Correctly gives the position as carbon 3.

B1 (c) · 1 mark · States the correct IUPAC name as '3-methylpentane'.

Worked solution

a) The longest continuous chain has 5 carbons, which is 'pentane'.

b) The side chain is a methyl group () attached to carbon 3.

c) The full IUPAC name is 3-methylpentane.

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