Addition polymerisation
4 marks · NormalAddition polymers such as poly(chloroethene) are made from small molecules called monomers.
Name the type of reaction used to make poly(chloroethene).
Describe the role of an initiator in the preparation of addition polymers.
Draw the structure of chloroethene, the monomer used to make poly(chloroethene).
State one use of poly(chloroethene).
Work this out on paper, then compare with the answer and worked solution below. With a free account you can submit written answers for marking.
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(a) Addition polymerisation · must show Identifies 'addition polymerisation'
(b) The initiator starts the reaction/opens the double bond so monomers can join together. It is used up in the reaction. · must show Mentions initiator starts the process/reaction or opens the double bond, Not called a catalyst
(c) Displayed structure of chloroethene (H2C=CHCl) · must show Structure must show C=C, with one H and one Cl on second carbon, two H on first
(d) E.g. used to make pipes, cable insulation, or window frames. · must show Valid use of poly(chloroethene)
Also accept: Polyvinyl chloride for poly(chloroethene); Accept wire insulation, pipes, etc.
Common mistakes: Calling the reaction 'condensation polymerisation'; Calling the initiator a 'catalyst'
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Marking points
B1 (a) · 1 mark · Identifies addition polymerisation
B2 (b) · 1 mark · Describes that the initiator starts the process or opens the double bond
B3 (c) · 1 mark · Draws correct structure for chloroethene
B4 (d) · 1 mark · States a valid use of poly(chloroethene)
Worked solution
a) Addition polymerisation
b) An initiator starts the reaction by opening the double bond in the monomer, allowing them to join into a chain. It is used up in the reaction.
c) Chloroethene structure (displayed structure as above).
d) Used to make pipes, window frames, or insulation for wires.