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Question 43 of 130 in Alcohols

Ethanol can be oxidised by heating with potassium dichromate(VI) in dilute sulfuric acid

2 marks · Easy

A student observes the colour change when ethanol is heated with potassium dichromate(VI) in dilute sulfuric acid. Explain why the green colour appears during this reaction.

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The green colour appears because potassium dichromate(VI) is reduced to chromium(III) ions (Cr^{3+}) during the oxidation of ethanol.

Must show: reduction of dichromate(VI), formation of Cr^{3+} ions, link to green colour

Also accept: Green colour indicates Cr3+ ions are formed.; Potassium dichromate(VI) is reduced, causing a colour change to green due to chromium(III) ions.

Common mistakes: Ethanol turns green.; It is due to ethanoic acid.

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Marking points

M1 · 1 mark · Mentions that potassium dichromate(VI) is reduced when ethanol is oxidised.

A1 · 1 mark · Explains that the green colour is due to chromium(III) ions (Cr3+).

Worked solution

During the reaction, potassium dichromate(VI) is reduced as it oxidises ethanol.

This reduction produces chromium(III) ions (Cr^{3+}), which make the solution green.

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