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Question 174 of 185 in Introduction to Organic Chemistry

Introduction to Organic Chemistry

5 marks · Easy

The molecule pentane belongs to a homologous series of organic compounds.

(a)

State what is meant by a 'homologous series' in organic chemistry.

[1 mark]
(b)

Give the general formula for the homologous series that pentane belongs to.

[1 mark]
(c)

Write the molecular formula for pentane.

[1 mark]
(d)

Draw the displayed formula for pentane.

[2 marks]

Work this out on paper, then compare with the answer and worked solution below. With a free account you can submit written answers for marking.

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(a) A series of organic compounds with the same functional group, similar chemical properties, and each member differing by a –CH2– unit.

(b) CnH2n+2

(c) C5H12

(d) — · must show 5 carbon atoms in a straight chain, each with enough hydrogen atoms to make 4 bonds for C, 1 for H; all bonds shown

Common mistakes: Naming the wrong general formula; Omitting required bonds in displayed formula

Show mark scheme and worked solution

Marking points

B1 (a) · 1 mark · Defines a homologous series as a set of organic compounds with the same functional group, similar properties, and each differing by –CH2–.

B1 (b) · 1 mark · States the correct general formula: CnH2n+2 for alkanes.

B1 (c) · 1 mark · Gives correct molecular formula for pentane: C5H12.

B1 (d) · 2 marks · Displayed formula: All C and H atoms shown, all bonds included, correct number of each. Award 1 for correct chain, 1 for all bonds correctly drawn.

Worked solution

a) A homologous series is a family of organic compounds with the same functional group, similar chemical properties, and each member differs from the next by a –CH2– group.

b) The general formula for alkanes (the series pentane belongs to) is CnH2n+2.

c) Pentane has 5 carbon atoms. Using the formula: n = 5, so the formula is C5H12.

d) Displayed formula:

Each carbon is attached to enough H atoms to make 4 bonds in total. Draw all single bonds between atoms.

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