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Question 169 of 185 in Introduction to Organic Chemistry

Some chemical reactions of organic compounds

4 marks · Normal

The following two reactions involve organic compounds:

(a)

CH4(g) + Cl2(g) → CH3Cl(g) + HCl(g). State the type of reaction and explain why it is classified as this type.

[2 marks]
(b)

C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(l). State the type of reaction and explain your answer.

[2 marks]

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(a) Substitution; because a hydrogen atom in methane is replaced by a chlorine atom.

(b) Combustion; because propane reacts with oxygen to form carbon dioxide and water, releasing energy.

Common mistakes: Calling combustion a substitution or addition; Forgetting to explain that in substitution a group/atom is replaced; Not stating oxygen is involved in combustion

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Marking points

B1 (a) · 1 mark · States reaction is substitution.

B2 (a) · 1 mark · Explains that a hydrogen atom is replaced by a different atom (chlorine).

B3 (b) · 1 mark · States reaction is combustion.

B4 (b) · 1 mark · Explains that the compound combines with oxygen to produce carbon dioxide and water (or references burning).

Worked solution

(a) This is a substitution reaction. A hydrogen atom in methane is replaced by a chlorine atom to give chloromethane and hydrogen chloride.

(b) This is a combustion reaction. Propane reacts with oxygen, producing carbon dioxide and water, which is typical of combustion reactions involving organic compounds.

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