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Question 698 of 785 in Organic Chemistry

How to deduce the polymerisation reaction for any alkene

5 marks · Hard

A polymer contains the following repeat unit:

(a)

Draw the displayed formula of the monomer used to make this polymer.

[2 marks]
(b)

Write the name and molecular formula of this monomer.

[2 marks]
(c)

Explain why the double bond in the monomer is important for the polymerisation reaction.

[1 mark]

Work this out on paper, then compare with the answer and worked solution below. With a free account you can submit written answers for marking.

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(a) — · must show C=C double bond between two carbons, One Br atom on one of the carbons, Each carbon has appropriate number of H atoms (CH2=CHBr)

(b) bromoethene; CH2=CHBr

(c) The double bond allows the molecules to join together; it opens up so monomers can link to form the polymer chain.

Common mistakes: Forgetting to include the double bond in the monomer; Incorrect placement of Br atom; Confusing repeat unit with monomer

Show mark scheme and worked solution

Marking points

B1 (a) · 1 mark · Displayed formula for bromoethene with correct structure (C=C, Br attached to one C, correct number of hydrogens).

B2 (a) · 1 mark · All bonds and atoms correctly shown (clear double bond, correct valency).

B3 (b) · 1 mark · Correct name: bromoethene.

B4 (b) · 1 mark · Correct molecular formula: CH2=CHBr.

B5 (c) · 1 mark · States that the double bond opens to allow molecules to join/polymerise.

Worked solution

a) The monomer is CH2=CHBr. The displayed formula is:

b) Name: bromoethene; Molecular formula: CH2=CHBr

c) The double bond breaks and allows each monomer molecule to connect, forming the long polymer chain.

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