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Question 130 of 442 in Physical Chemistry

Experiments to measure the rate of reaction

4 marks · Normal
Time / minMass of CO2 lost / g
00.00
10.32
20.54
30.63
40.66
50.67
(a)

Calculate the average rate of reaction between 0 and 2 minutes (give your answer in g/min).

[1 mark]
(b)

Calculate the average rate of reaction between 2 and 5 minutes (give your answer in g/min).

[1 mark]
(c)

State and explain the main trend in the rate of reaction as time increases.

[2 marks]

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(a) 0.27 g/min · must show correct calculation: (0.54-0.00)/2

(b) 0.043 g/min · must show correct calculation: (0.67-0.54)/3

(c) The rate of reaction decreases as time increases, because the reactants are being used up and so there are fewer collisions between particles. · must show states rate decreases with time, explains reason using reactant use/concentration/collisions

Common mistakes: confuses end and start values

Show mark scheme and worked solution

Marking points

A1 (a) · 1 mark · Correctly calculates average rate from 0–2 min: (0.54−0.00)/2 = 0.27 g/min

A2 (b) · 1 mark · Correctly calculates average rate from 2–5 min: (0.67−0.54)/3 = 0.043 g/min

B1 (c) · 1 mark · States there is a decrease in rate of reaction as time goes on.

M1 (c) · 1 mark · Explains the trend using reactant use or concentration decrease, or collision theory.

Worked solution

a) Average rate (0–2 min) = (0.54−0.00)/2 = 0.27 g/min b) Average rate (2–5 min) = (0.67−0.54)/3 = 0.13/3 = 0.043 g/min c) The rate of reaction decreases over time because the acid is used up, so fewer reactant particles are available for collisions.

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