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Question 99 of 442 in Physical Chemistry

Calculation of enthalpy changes of reaction using bond energies

3 marks · Easy

The table below gives bond energies (kJ/mol):

BondBond energy / kJ mol^{-1}
C–C151
C–H413
H–H436

Use these values to answer the following about the reaction:

(a)

List all the bonds broken and all formed in this reaction.

[1 mark]
(b)

Calculate the total energy required to break bonds in the reactant.

[1 mark]
(c)

Calculate the enthalpy change (ΔH) for the reaction.

[1 mark]

Work this out on paper, then compare with the answer and worked solution below. With a free account you can submit written answers for marking.

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(a) Bonds broken: 1 C–C bond and 2 C–H bonds; Bonds formed: 1 C=C bond (not given, so omitted, but required energy ignored for this specific question), 1 H–H bond.

(b) 977 kJ

(c) 541 kJ/mol

Common mistakes: Confusing bonds broken with bonds formed

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Marking points

B1 (a) · 1 mark · Correctly lists all relevant bonds broken and formed.

M1 (b) · 1 mark · Calculates total energy required to break bonds (151 + 2×413).

A1 (c) · 1 mark · Calculates ΔH (977 – 436 = 541 kJ/mol), with sign.

Worked solution

a) Bonds broken: 1 C–C bond, 2 C–H bonds. Bonds formed: 1 H–H bond. (If C=C energy given, include C=C bond formation.)

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