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Question 101 of 442 in Physical Chemistry

Calculation of enthalpy changes of reaction using bond energies

3 marks · Easy

Bond energies are given below:

BondBond energy / kJ mol^{-1}
N≡N946
H–H436
N–H388

Use the bond energies to answer the following about the reaction:

(a)

Calculate the total energy needed to break all bonds in the reactants.

[1 mark]
(b)

Calculate the total energy released by forming all bonds in the products.

[1 mark]
(c)

Determine the enthalpy change (ΔH) for the reaction.

[1 mark]

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(a) 946 + (3 × 436) = 946 + 1308 = 2254 kJ

(b) 2 × (3 × 388) = 6 × 388 = 2328 kJ

(c) –74 kJ/mol

Common mistakes: Wrong sign on final answer; Missing units or steps

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Marking points

M1 (a) · 1 mark · Correctly calculates total bond breaking energy (946 + 3 × 436 = 2254 kJ).

M2 (b) · 1 mark · Correctly calculates total bond forming energy (6 × 388 = 2328 kJ).

A1 (c) · 1 mark · Correctly calculates ΔH = 2254 – 2328 = –74 kJ/mol with correct sign.

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