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Question 236 of 442 in Physical Chemistry

How does a catalyst work?

3 marks · Easy
(a)
Values for a reaction profile.
DescriptionEnergy (kJ/mol)
Reactants120
Peak without catalyst200
Peak with catalyst140
Products60

Calculate the activation energy without a catalyst.

[1 mark]
(b)

What is the activation energy with a catalyst?

[1 mark]
(c)

Describe how the catalyst affects the reaction profile diagram, using the values from the table.

[1 mark]

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(a) 80 kJ/mol

(b) 20 kJ/mol

(c) The catalyst lowers the activation energy from 80 kJ/mol to 20 kJ/mol; on the diagram the peak is lower.

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Marking points

M1 (a) · 1 mark · Calculates activation energy without catalyst as 200 - 120 = 80 kJ/mol.

M1 (b) · 1 mark · Calculates activation energy with catalyst as 140 - 120 = 20 kJ/mol.

B1 (c) · 1 mark · Describes the catalyst lowers activation energy/peak from 80 to 20 kJ/mol. (follow-through)

Worked solution

(a) Activation energy without catalyst = Peak (no catalyst) - Reactants = 200 - 120 = 80 kJ/mol.

(b) Activation energy with catalyst = Peak (with catalyst) - Reactants = 140 - 120 = 20 kJ/mol.

(c) The catalyst lowers the activation energy shown by the lower peak (from 80 to 20 kJ/mol) on the diagram.

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