SubjectCover

Question 61 of 144 in Reversible Reactions and Equilibria

Changing the pressure

2 marks · Easy

Consider the following equilibrium:

Explain, with a reason, what would happen to the position of equilibrium if the pressure is decreased.

Work this out on paper, then compare with the answer and worked solution below. With a free account you can submit written answers for marking.

Show answer

The equilibrium will shift to the left (to the side with more gaseous molecules), because decreasing pressure favours the side with more gas molecules.

Also accept: It shifts to the side with the greater number of gas molecules; It shifts towards the reactants; It shifts left; More SO2 and O2 will be formed

Common mistakes: It does not shift; It shifts to the side with fewer molecules

Show mark scheme and worked solution

Marking points

M1 · 1 mark · Identifies that the equilibrium shifts left (towards more moles of gas)

M1 · 1 mark · Gives a clear reason linked to number of gaseous molecules and/or pressure

Worked solution

There are 2 moles of gas on the left (SO_2(g) + O_2(g)) and 2 moles on the right (2SO_3(g)). (Correction: Both sides have 2 moles; pressure change has no effect.)

Actually, since there are equal numbers of gas molecules on both sides, changing pressure will have no effect on the position of equilibrium.

Report a problem with this question
What's wrong?