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Question 65 of 144 in Reversible Reactions and Equilibria

Changing the pressure

2 marks · Easy

The following reaction is at equilibrium at 400 K:

If the total pressure is doubled, predict the effect on the amount of A(g) formed at equilibrium. Show your reasoning.

(a)

Calculate the number of gaseous molecules on each side of the equation.

[1 mark]
(b)

State whether the amount of A(g) at equilibrium will increase, decrease, or stay the same. Explain your answer.

[1 mark]

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(a) Left: 1, Right: 2

(b) The amount of A(g) will decrease, because increasing pressure favours the side with fewer gas molecules (A2(g)).

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Marking points

B1 (a) · 1 mark · States 1 gaseous molecule on the left, 2 on the right

M1 (b) · 1 mark · Correct prediction and explanation based on pressure and number of molecules

Worked solution

(a) Left: 1 gas molecule (A_2(g)); Right: 2 gas molecules (2A(g)).

(b) Increasing pressure will decrease the amount of A(g) at equilibrium, because the change favours the side with fewer gas molecules (A_2(g)).

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