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Question 114 of 144 in Reversible Reactions and Equilibria

Adding a catalyst

2 marks · Hard

Explain why the addition of a catalyst does not affect the position of equilibrium in a reversible reaction.

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Because a catalyst increases the rate of both the forward and reverse reactions by the same amount, so the relative amounts of reactants and products at equilibrium remain unchanged.

Also accept: A catalyst speeds up both reactions equally, so the proportion of products and reactants at equilibrium is not changed.

Common mistakes: Saying a catalyst pushes equilibrium to the right/left.; Omitting reference to both directions.

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Marking points

B1 · 1 mark · States catalyst increases both forward and reverse reaction rates equally.

B2 · 1 mark · States that the position of equilibrium/remains unchanged (relative amounts/products and reactants stay the same).

Worked solution

A catalyst works by providing an alternative pathway for the reaction, increasing the rate at which both forward and reverse reactions occur by the same proportion. Therefore, the equilibrium position does not shift since neither the forward nor the reverse reaction is favoured more than the other.

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