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Pearson Edexcel International GCSE (9–1) · CHEMISTRY · Chapter

Rates of Reaction

164 practice questions

Topics covered

Practice questions

11–20 of 27 · Hard

  1. Question 11

    5 marks · Hard

    A student prepares dilute hydrochloric acid for a reaction by adding water to a known volume of 2.50 mol/dm³ hydrochloric acid. She then uses the solution to react with marble chips.

    (a)

    She mixes 10.0 cm³ of 2.50 mol/dm³ acid with 30.0 cm³ of water to make 40.0 cm³ of solution. Calculate the concentration, in mol/dm³, of the hydrochloric acid after dilution.

    [2 marks]
    (b)

    She repeats the process, using 25.0 cm³ of 2.50 mol/dm³ acid topped up with water to 40.0 cm³. Calculate the new concentration, in mol/dm³, after dilution.

    [2 marks]
    (c)

    State the formula used to calculate the final concentration when diluting a solution.

    [1 mark]
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  2. Question 12

    2 marks · Hard

    An experiment produced 0.46 g of carbon dioxide in the first 20 seconds during the reaction of marble chips with dilute hydrochloric acid. Calculate the average rate of carbon dioxide production, giving your answer in g/s. Show your working.

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  3. Question 13

    2 marks · Hard

    A chemical reaction between nitrogen and hydrogen gases is taking place in a sealed vessel. The pressure inside the vessel is increased while the temperature remains constant.

    Describe and explain what happens to the rate of reaction when the pressure is increased.

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  4. Question 14

    5 marks · Hard

    A student investigates the effect of pressure on two reactions:

    (a)

    Reaction 1: Two solid powders are mixed together in a sealed container. Predict what happens to the rate of reaction if the pressure is increased. Explain your answer using particle theory.

    [3 marks]
    (b)

    Reaction 2: Two liquids are mixed together. Explain, using your knowledge of particle arrangement, why increasing the pressure has little effect on the rate of reaction.

    [2 marks]
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  5. Question 15

    2 marks · Hard

    A reaction takes place between two gases. The pressure is increased by decreasing the volume of the container.

    Explain why this leads to a faster reaction rate, using ideas about particle collisions.

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  6. Question 16

    2 marks · Hard

    State two features that are always true for catalysts when used in a chemical reaction.

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  7. Question 17

    5 marks · Hard

    A student investigates the reaction below:

    (a)

    Describe how the student could show that manganese(IV) oxide acts as a catalyst in this reaction.

    [2 marks]
    (b)

    After the reaction, the student filters, dries, and reweighs the manganese(IV) oxide. The mass is unchanged. Explain why this result supports the conclusion that manganese(IV) oxide is a catalyst.

    [2 marks]
    (c)

    State why only a small amount of catalyst is usually needed for a reaction.

    [1 mark]
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  8. Question 18

    2 marks · Hard

    Explain why the same catalyst cannot usually be used for every type of chemical reaction.

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  9. Question 19

    2 marks · Hard

    The diagram below shows a reaction profile for an exothermic reaction. The activation energy for the uncatalysed reaction is much larger than for the catalysed reaction.

    Geometry diagram with points Reactants, Products, Peak without catalyst, Peak with catalystReactantsProductsPeak without catalystPeak with catalyst
    Reaction profile for an exothermic reaction (uncatalysed and catalysed).

    Describe what the dashed line on this diagram represents. Explain how a catalyst causes this change.

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  10. Question 20

    5 marks · Hard

    A student draws the following reaction profile diagram for a certain chemical reaction:

    Geometry diagram with points Reactants, Products, Peak without catalyst, Peak with catalystReactantsProductsPeak without catalystPeak with catalyst
    Reaction profile for a chemical reaction.

    Use the diagram to answer the questions below.

    (a)

    State the term used for the energy difference from the reactants up to the peak without a catalyst.

    [1 mark]
    (b)

    Describe how the diagram shows the effect of a catalyst on the reaction.

    [2 marks]
    (c)

    Explain why many more particles in the reaction mixture can react when a catalyst is used, referring to the activation energy.

    [2 marks]
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